Can I use it to harden my origami??

You could try it, but I don't think it would work that well. It's not that thick.

Can I spray this over a wooden frame painted with acrylic paint?

Yes, you can. As long as the paint is acrylic, it's fine. The spray will also seal the wood. Use a few coats.

can i use this to seal off a porous chalkboard? Thank you!

I am not sure. I have only used it to seal in acrylic paint on jewelry.

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