Can I just buy it once and try it?

Yes, if you buy it through Amazon it's a one time purchase.

is this product american dental association (ADA) approved?

Yes, it was invented by a Dentist.

has anyone that has bonding used this product?

I have several bonds, it helps keep them white and has no adverse affect.

To a degree, porcelain caps can only be whitened to their original color. "White" fillings that have become discolored will remain discolored.

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